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Hi Jim
and Jere,
I
found similar structures in the early diagenetic recrystallisation of crustacean
exoskeletons. They tended to form tight-ball rosettes, some hemispherical and
twinned (or paired). The strucutres were up to 150 microns in size and made of
calcite rather the than phosphate of the later diagenesis of the cuticle. It
appears that the structures may have been bacterially mediated. Their size and
form appear to depend on the crystalline structure of the skeleton and the
organic content. I found that the structures appeared to form in high
concentrations of phosphatic solutions (unpublished, but mentioned in my PhD
thesis). There are also secondary 0.35micron spherical structures that form
phosphatic replacements of the ultrastructure of the skeleton. These area also
thought to be bacterially mediated. I haven't kept up with the literature
on this, but I would search through papers by DEG Briggs over the last ten
years.
Neil
************************************ Dr Neil DL Clark Curator of Palaeontology Hunterian Museum University of Glasgow GLASGOW G12 8QQ tel: +44 (0) 141 330 3599 web sites: http://www.hunterian.gla.ac.uk/ http://www.scottishgeology.com/ http://www.geologyglasgow.org.uk/ http://www.hmag.gla.ac.uk/Neil/ *********************************************
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